Known for its silver, shiny appearance, chromium is used to coat cars,
stoves and other appliances to protect them from corrosion and to
improve their looks. Chromium's high melting point and stable structure
also make it useful in the textile and refractory industries. When
combined with other elements, chromium makes vibrant colors and is used
as a dye, which is what originally earned it its name from the Greek
word chroma for "color."
It is naturally found in compounds in the earth's crust. However,
consuming high levels of chromium in polluted drinking water or inhaling
fumes of the heated element can cause ulcers, cancer and other health
problems.
Just the facts
Atomic number (number of protons in the nucleus): 24
Number of natural isotopes (atoms of the same element with a different number of neutrons): 4
Most common isotope: Cr-52
Discovery of chromium
French chemist Louis Nicolas Vauquelin first isolated chromium from a
bright red mineral called Siberian red lead, now known as lead chromate
(PbCrO4) in 1797. According to John Emsley in his book, "Nature’s Building Blocks: An A-Z Guide to the Elements"
(Oxford University Press, 1999), it took Vauquelin a year before he was
able to precipitate out the lead and obtain pure chromium. He mixed the
chromium in a variety of solutions and was intrigued by the many colors
it produced, thereby naming the element after the Greek word chromameaning "color."
Sources of chromium
Chromium is the 21st most common element found in the Earth's crust,
but it is not found in its free metal form. Instead, it is principally
found in chromite ore, according to Robert E. Krebs in his book, "The History and Use of Our Earth’s Chemical Elements: A Reference Guide"
(Greenwood Publishing Group, 2006). Chromite is mined in Zimbabwe,
Russia, New Zealand, Turkey, Iran, Albania, Finland, the Philippines and
Madagascar. About 20,000 tons of chromium metal are produced each year,
and there are still about a billion tons of unexploited deposits in
Greenland, Canada, and the United States, according to Emsley. Chromium
metal is then obtained by heating the chromite ore in the presence of
aluminum or silicon, according to the Jefferson Lab.
Properties of chromium
Chromium is a transition metal in Group 6 on the Periodic Table of
Elements. In its pure form, chromium is a silvery, lustrous, hard metal
that has a high polish, ideal for electroplating.
The most important chromium compounds are the chromates of sodium and
potassium, the dichromates, and potassium and ammonium chrome alums,
according to the Los Alamos National Laboratory. Chromium compounds are toxic and should be handled with care.
Chromium compounds are all vividly colored and are used as pigments —
bright green, yellow, red and orange. Rubies are red because of
chromium, and glass treated with chromium has an emerald green color,
according to the Royal Society of Chemistry (RSC).
Used for protection and beauty
Using a technique called electroplating, a thin layer of chromium can
coat metal and plastic objects, including car parts and household
appliances, to give a shiny, attractive finish. For example, automotive
designers use chrome rims and wheels to spruce up their cars. Chrome
plating is not only used for looks; because the chromium forms a
protective oxide layer on the surface, chrome-plated objects resist
corrosion, according to Krebs.
Stainless steel is an alloy of iron and at least 10.5 percent chromium.
It is highly resistant to corrosion. It is used in kitchen cutlery,
appliances and cookware such as stainless steel pans and skillets.
About 90 percent of leather is chrome tanned, according to Emsley.
During this process, chromium sulfate is used to treat animal skin and
turn it into leather that is resistant to hot water that can cause
degradation.
Kilns and furnaces use bricks made of chromite ore, which retains
strength at high temperatures. The textile industry uses chromium ions
to help adhere dyes to fabric. Chromium's high melting point, moderate
thermal expansion and crystalline structure stability make it suitable
for these purposes.
Dangerous in excess
Though its specific role in humans is unclear, studies have shown that
chromium is an essential trace element that is found in RNA and helps
the body to use glucose. Chromium is most concentrated in the placenta,
and its presence in the body decreases with age.
A safe amount is about 1 milligram per day, according to the RSC. Foods
such as brewer's yeast, wheat germ and kidney are rich in chromium.
However, it is poisonous in excess.
In the 2000 film "Erin Brockovich," Julia Roberts portrays an
environmental activist and legal clerk who leads a case against a gas
and electric company for contaminating drinking water with chromium(VI),
a toxic compound known to cause cancer,
according to the U.S. Occupational Safety and Health Administration
(OSHA). Though Brockovich won the case in real life and in the movie, scientists have criticized
her lack of evidence showing that chromium(VI), and not other factors,
was the cause of the numerous health issues including cancer in the
community of Hinkley, Calif.
However, several studies in the past few
years have linked chromium(VI) in tap water to cancer and the EPA has set a drinking water concentration limit for the element to protect public health.
Excessive exposure to chromium can also cause chrome ulcers,
particularly when working with it for months while chrome-plating or
leather tanning, according to Emsley. Chrome ulcers are itchy and raw
holes in the skin or the stomach. If dust containing chromium is
inhaled, industrial workers are more prone to ulcers in the nasal cavity
and lung cancer. Additionally, a 2017 study published in European Journal of Clinical Nutrition linked high levels of urinary chromium to cardiovascular disease and diabetes.
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